Point and Diffuse Loads of Selected Pollutants in the River Rhine and Its Main Tributaries

The research described in this working paper was conducted for the study "Sources of Chemical Pollution in the Rhine Basin," a collaborative effort between IIASA and the Netherlands National Institute for Public Health and Environmental Protection (RIVM). The goal of the study was to determine, by mass balance analysis, the inputs and outputs to the Rhine Basin over the time period 1950-2010. Particular attention was given to "cradle-to-grave" analysis in which the pollutants are traced from their pathways through the industrial economy and into the environment. For the historical analysis, it was necessary to estimate emissions from various industrial sectors (point sources) and runoff from urban, agricultural and forested lands (diffuse sources). The analysis is hindered, however, by the scarcity of historical data on sources of emission. On the other hand, the Rhine River has been intensively monitored for heavy metals since the early 1970s, and for nutrients and other hydrological parameters since the 1950s. These data provide a basis for making reasonable estimates of inputs to the river in previous decades. Prior to the analysis presented herein, no comprehensive investigation of the long-term time series of chemical loads to the river had been undertaken. This working paper not only quantifies the total loads of the various chemicals over time. It also subdivides the loads into the point-source and diffuse fractions, applying a new methodology developed by the senior author of this paper. With the estimates provided here, it is possible to calibrate the emission factors assumed for industrial and diffuse sources. The paper thus makes an invaluable contribution of the major goals of the study

The life cycle of starbursting circumnuclear gas discs

High-resolution observations from the sub-mm to the optical wavelength regime resolve the central few 100pc region of nearby galaxies in great detail. They reveal a large diversity of features: thick gas and stellar discs, nuclear starbursts, in- and outflows, central activity, jet interaction, etc. Concentrating on the role circumnuclear discs play in the life cycles of galactic nuclei, we employ 3D adaptive mesh refinement hydrodynamical simulations with the RAMSES code to self-consistently trace the evolution from a quasi-stable gas disc, undergoing gravitational (Toomre) instability, the formation of clumps and stars and the disc's subsequent, partial dispersal via stellar feedback. Our approach builds upon the observational finding that many nearby Seyfert galaxies have undergone intense nuclear starbursts in their recent past and in many nearby sources star formation is concentrated in a handful of clumps on a few 100pc distant from the galactic centre. We show that such observations can be understood as the result of gravitational instabilities in dense circumnuclear discs. By comparing these simulations to available integral field unit observations of a sample of nearby galactic nuclei, we find consistent gas and stellar masses, kinematics, star formation and outflow properties. Important ingredients in the simulations are the self-consistent treatment of star formation and the dynamical evolution of the stellar distribution as well as the modelling of a delay time distribution for the supernova feedback. The knowledge of the resulting simulated density structure and kinematics on pc scale is vital for understanding inflow and feedback processes towards galactic scales.Comment: accepted by MNRA

Scanning rotational Raman lidar at 355 nm for the measurement of tropospheric temperature fields

International audienceFor high-resolution measurements of temperature fields in the atmospheric boundary layer and the lower free troposphere a scanning eye-safe lidar which deploys the rotational Raman technique at 355 nm was developed. To optimize the filters of the receiver for both high nighttime and daytime performance, detailed simulation studies have been performed. The receiver is fiber-coupled to a sequential setup of multicavity interference filters used under small angles of incidence. Examples of nighttime and daytime measurements with the system which has a total power-aperture-efficiency product of 0.006 W m2 are presented. Noontime temperature measurements with a temporal resolution of 60 s result in 1-sigma statistical temperature uncertainty of <1 K up to 1 km height and <2 K up to 2 km height. With an integration time of 60 min and a gliding average of 750 m a 1-sigma statistical temperature uncertainty of <1 K up to 14 km height is achieved during night

Light entrained rhythmic gene expression in the sea anemone Nematostella vectensis : the evolution of the animal circadian clock

© The Authors, 2010. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in PLoS One 5 (2010): e12805, doi:10.1371/journal.pone.0012805.Circadian rhythms in behavior and physiology are the observable phenotypes from cycles in expression of, interactions between, and degradation of the underlying molecular components. In bilaterian animals, the core molecular components include Timeless-Timeout, photoreceptive cryptochromes, and several members of the basic-loop-helix-Per-ARNT-Sim (bHLH-PAS) family. While many of core circadian genes are conserved throughout the Bilateria, their specific roles vary among species. Here, we identify and experimentally study the rhythmic gene expression of conserved circadian clock members in a sea anemone in order to characterize this gene network in a member of the phylum Cnidaria and to infer critical components of the clockwork used in the last common ancestor of cnidarians and bilaterians. We identified homologs of circadian regulatory genes in the sea anemone Nematostella vectensis, including a gene most similar to Timeout, three cryptochromes, and several key bHLH-PAS transcription factors. We then maintained N. vectensis either in complete darkness or in a 12 hour light: 12 hour dark cycle in three different light treatments (blue only, full spectrum, blue-depleted). Gene expression varied in response to light cycle and light treatment, with a particularly strong pattern observed for NvClock. The cryptochromes more closely related to the light-sensitive clade of cryptochromes were upregulated in light treatments that included blue wavelengths. With co-immunoprecipitation, we determined that heterodimerization between CLOCK and CYCLE is conserved within N. vectensis. Additionally, we identified E-box motifs, DNA sequences recognized by the CLOCK:CYCLE heterodimer, upstream of genes showing rhythmic expression. This study reveals conserved molecular and functional components of the circadian clock that were in place at the divergence of the Cnidaria and Bilateria, suggesting the animal circadian clockwork is more ancient than previous data suggest. Characterizing circadian regulation in a cnidarian provides insight into the early origins of animal circadian rhythms and molecular regulation of environmentally cued behaviors.The project described was supported by Award Number F32HD062178 to AMR from the Eunice Kennedy Shriver National Institute of Child Health and Human Development and the Tropical Research Initiative of the Woods Hole Oceanographic Institution

Reactive melt infiltration of silicon-molybdenum alloys into microporous carbon preforms

Investigations on the reactive melt infiltration of silicon-1.7 and 3.2 at.% molybdenum alloys into microporous carbon preforms have been carried out by modeling, differential thermal analysis (DTA), and melt infiltration experiments. These results indicate that the pore volume fraction of the carbon preform is a very important parameter in determining the final composition of the reaction-formed silicon carbide and the secondary phases. Various undesirable melt infiltration results, e.g. choking-off, specimen cracking, silicon veins, and lake formation, and their correlation with inadequate preform properties are presented. The liquid silicon-carbon reaction exotherm temperatures are influenced by the pore and carbon particle size of the preform and the compositions of infiltrants. Room temperature flexural strength and fracture toughness of materials made by the silicon-3.2 at.% molybdenum alloy infiltration of medium pore size preforms are also discussed

Theoretical considerations for Reaction-Formed Silicon Carbide (RFSC) formation by molten silicon infiltration into slurry-derived preforms

For reaction-formed silicon carbide (RFSC) ceramics produced by silicon melt infiltration of porous carbon preforms, equations are developed to relate the amount of residual silicon to the initial carbon density. Also, for a slurry derived preform containing both carbon and silicon powder, equations are derived which relate the amount of residual silicon in the RFSC to the relative density of the carbon in the preform and to the amount of silicon powder added to the slurry. For a porous carbon preform that does not have enough porosity to prevent choking-off of the silicon infiltration, these results show that complete silicon infiltration can occur by adding silicon powder to the slurry mixture used to produce these preforms

Relationships between skin follicle characteristics and fibre properties of Suri and Huacaya alpacas and Peppin Merino sheep

We aimed to quantify the number, type and arrangement of skin follicles in Huacaya and Suri alpaca skin and correlate their follicle characteristics with fibre traits of harvested fibre and compared these relationships with those of Merino sheep. Fibre and skin samples were collected from the mid-side of 12 Huacaya alpacas, 24 Suri alpacas and 10 Merino sheep. The mean fibre diameter (MFD &plusmn; s.e.) of the Huacaya and Suri were: 35.5 &plusmn; 0.9 and 28.3 &plusmn; 1.0 &mu;m, respectively. The follicle groups found for alpacas were very different from the normal trio of primary follicles found in sheep and goats. The follicle group of the alpacas consisted of a single primary follicle surrounded by a variable number of secondary follicles. The mean &plusmn; s.e. primary follicle density was 3.1 &plusmn; 0.3 and 2.7 &plusmn; 0.1 follicles/mm2 for Huacaya and Suri, respectively. The mean &plusmn; s.e. secondary follicle density (SFD) was 13.7 &plusmn; 1.2 and 17.5 &plusmn; 0.6 follicles/mm2 for Huacaya and Suri, respectively. The mean &plusmn; s.e. ratio of secondary to primary follicles (S/P ratio) was 5.1 &plusmn; 0.5 for the Huacaya and 7.3 &plusmn; 0.2 for the Suri alpacas. The sheep had higher S/P ratios and SFD, lower MFD and produced significantly heavier fleeces. The key correlations found between traits in alpacas include a negative correlation between SFD and MFD (r = &ndash;0.71, P = 0.001) and a negative correlation between S/P ratio and MFD (r = &ndash;0.44, P = 0.003) and a positive correlation between S/P ratio and total follicle density (r = 0.38, P = 0.010). The study revealed that important relationships exist between alpaca skin follicle characteristics and fibre characteristics. It was the number of secondary follicles in a group that imparts density and a corresponding reduced MFD.<br /

Nutrient Balances of Rewetted Fens – Groundwater Lysimeter Results

With the raising of groundwater levels to protect fens and the climate, there may be a risk of nutrients, such as nitrogen or potassium, leaching into the groundwater. Great amounts of nutrients, which are accumulated largely by peat forming plants like Phragmites australis and Carex spec., are conveyed into rewetted fens through high amounts of introduced water. Nitrogen leaching into the groundwater is very low even at the beginning of flooding and there is no sudden, pronounced leaching. Only a portion of potassium is taken up by plants whereas the rest might be found in the groundwater. Increasing nutrient inputs must be expected as soon as more contaminated water is added contributing to the regeneration of groundwater and increasing the pollution with nutrients at once